Catalyst Initiation in the Oscillatory Carbonylation Reaction
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چکیده
منابع مشابه
The Effect of Temperature on Selectivity in the Oscillatory Mode of the Phenylacetylene Oxidative Carbonylation Reaction
Reaction temperature plays a major role in product selectivity in the oscillatory mode of the palladium-catalyzed phenylacetylene oxidative carbonylation reaction. At 40 °C, dimethyl (2Z)-2-phenyl-2-butenedioate is the major product whereas at 0 °C the major product is 5,5-dimethoxy-3-phenyl-2(5H)-furanone. The occurrence of oscillations in pH coincides with an increase in the rate of phenylace...
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ژورنال
عنوان ژورنال: International Journal of Chemical Engineering
سال: 2011
ISSN: 1687-806X,1687-8078
DOI: 10.1155/2011/518592